I heard that water is a medium for heat exchange how would a water manipulator use vapor to control air via temperature?

From the superpower wiki I heard that vapor is a medium for heat exchange, but when I did some research on it I found that heat exchange might need a closed system. In a fictional world how would a Water manipulator that can mess with vapor and ice change temperature to control air?

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I heard that water is a medium for heat exchange how would a water manipulator use vapor to control air via temperature?

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