Sulphur dioxide planet

Trying to create a planet with sulphur dioxide (which is heavier than oxygen I think) on a lower level and oxygen above it. Is this possible? Need something that is horrible on the bottom and want mobile fungi [yep, they have legs] scrambling up to get away from it into the oxygen. (So annoying to have to always use fungi or bacteria when you are looking for an extremophile. Fungi have been done to death.)

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Sulphur dioxide planet

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