Could extremophiles evolve intelligence?

This new idea/story includes an ancient subterranean race, but they need to survive harsh conditions. Developing a nervous system/brain is important. Are certain proteins necessary to form a complex brain or can they thrive on volcanic conditions to become sentient? (i.e. carbs/protein vs chemicals, in line with deep underwater life found near volcanic vents) Part of story below, as humans accidentally discover technology from another race indigenous to Earth, a secretive and well hidden species, hence an unknown subterranean world. Hope this question makes sense, as I need scientific explanations for the existence of this 50-million year old race with superior intelligence/technology. https://artidan007.wordpress.com/2016/11/26/black-knight-antarctic-dawn/

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Could extremophiles evolve intelligence?

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