What would cause life forms to be water soluble (i.e. witches)?

Suppose the Wicked Witch of the West was simply an alien life form that was stranded in Oz. She comes from a race of beings that are water soluble.

She would have to be able to resist a small amount of water, or else any contact with water vapors in the atmosphere would dissolve her. Yet, any significant amount of water (such as a cup of it), would instantly cause her to dissolve.

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What would cause life forms to be water soluble (i.e. witches)?

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